Catalytic Application of Biochar Functionalized Copper-<scp>l</scp>-histidine for the Chemo and Homoselective Conversion of Cyanides to Amides and Reduction of Nitroarenes to anilines

In our study, we aimed to use olive pomace, food industry waste, as biomass to produce biochar nanoparticles. The surface of the biochar was functionalized with the l-histidine ligand, and then cupric acetate was added to prepare Cu-l-histidine@biochar as a final catalyst for the chemo- and homoselective synthesis of amide and aniline derivatives. To characterize the novel catalyst, we employed various techniques. Another notable feature of this catalyst is its reusability, which maintained significant efficiency even after multiple uses in reactions.

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Publication Details

Journal
ACS Omega
Published
2024-11-19
DOI
https://doi.org/10.1021/acsomega.4c08465
Citations
4
Primary Topic
Nanomaterials for catalytic reactions
Type
article
Field-Weighted Citation Impact
1.00

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article

Catalytic Application of Biochar Functionalized Copper-l-histidine for the Chemo and Homoselective Conversion of Cyanides to Amides and Reduction of Nitroarenes to anilines

Mohammad Ali Zolfigol, Sepideh Jalali-Mola, Maryam Hajjami, Mahrokh Farrokh
4 citations
ACS Omega
Nanomaterials for catalytic reactions
1.00
article

Catalytic Application of Biochar Functionalized Copper-l-histidine for the Chemo and Homoselective Conversion of Cyanides to Amides and Reduction of Nitroarenes to anilines

Mohammad Ali Zolfigol, Sepideh Jalali-Mola, Maryam Hajjami, Mahrokh Farrokh
article en
4 citations

Abstract

In our study, we aimed to use olive pomace, food industry waste, as biomass to produce biochar nanoparticles. The surface of the biochar was functionalized with the l-histidine ligand, and then cupric acetate was added to prepare Cu-l-histidine@biochar as a final catalyst for the chemo- and homoselective synthesis of amide and aniline derivatives. To characterize the novel catalyst, we employed various techniques. Another notable feature of this catalyst is its reusability, which maintained significant efficiency even after multiple uses in reactions.

ACS OmegaVol. 9(48)
Bu-Ali Sina University (IR)
Bu-Ali Sina University
Openalex Percentile: Top 26%
Nanomaterials for catalytic reactions
1.00
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