Ultrafast Dual Activation of C(sp<sup>3</sup>)–H and C(sp<sup>2</sup>)–H Bonds in an Arc Plasma-Initiated Microdroplet
This study demonstrates a method that utilizes arc plasma-induced microdroplet reactions to synthesize dual-activated products with C(sp<sup>3</sup>)-N and C(sp<sup>2</sup>)-O bonds starting from C-H bonds. This innovative process utilizes arc- and microdroplet-generated hydroxyl radicals and water dimer radical cations, opening new possibilities for the multisite derivatization of small molecules.
Authors
- Ruiwen Wang
- Yuanji Gao (ORCID: https://orcid.org/0000-0001-9923-6360)
- Yuanjiang Pan (ORCID: https://orcid.org/0000-0003-2900-2600)
- Kaineng Huang
Institutions
- Sichuan Normal University (CN)
- Zhejiang University (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2024-11-19
- DOI
- https://doi.org/10.1021/acs.orglett.4c03782
- Citations
- 2
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.50
Funders
- National Natural Science Foundation of China