Ligand-controlled Rh( <scp>i</scp> )-catalyzed intramolecular alkyne sila-cyclization: divergent catalysis and mechanistic studies
A chemo-divergent Rh-catalyzed Si–C bond cleavage process was established for the synthesis of novel silacycles, wherein the cyclic silylmetal intermediates undergo highly efficient intramolecular sila-cyclization reactions under mild conditions.
Authors
- Li-Wen Xu
- Wei-Ke Zhu
- Zhenghe Xu (ORCID: https://orcid.org/0000-0001-8118-1920)
- Fei Ye (ORCID: https://orcid.org/0000-0002-0546-0239)
- Li Li (ORCID: https://orcid.org/0000-0001-5575-0894)
- Jia‐Wei Si
- Sui-Fang Peng
Institutions
- Hangzhou Normal University (CN)
- Lanzhou Institute of Chemical Physics (CN)
- Affiliated Hospital of Hangzhou Normal University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-11-19
- DOI
- https://doi.org/10.1039/d4qo02119c
- Citations
- 9
- Primary Topic
- Catalytic Alkyne Reactions
- Type
- article
- Field-Weighted Citation Impact
- 2.25