Testing ion exchange resin for quantifying bulk and throughfall deposition of macro- and micro-elements in forests

Abstract. Atmospheric deposition is a major nutrient influx in ecosystems, while high anthropogenic deposition may disrupt ecosystem functioning. Quantification of the deposition flux is required to understand the impact of such anthropogenic pollution. However, current methods to measure nutrient deposition are costly, labor-intensive and potentially inaccurate. Ion exchange resin (IER) appears to be a promising cost- and labor-effective method. The IER method is potentially suited for deposition measurements on coarse timescales and for areas with little rainfall and/or low elemental concentrations. The accuracy of the IER method is, however, hardly classified beyond nitrogen. We tested the IER method for bulk deposition and throughfall measurements of macro- and micro-elements, assessing resin adsorption capacity, recovery efficiency and field behavior. We show that IER is able to adsorb 100 % of Ca, Cu, Fe, K, Mg, Mn, P, S, Zn and NO3- and > 96 % of P and Na. Loading the resin beyond its capacity resulted mainly in losses of Na, P and NH4+, while losses of Ca, Cu, Fe, Mg, Mn and Zn were hardly detected. Heat (40 °C), drought and frost (−15 °C) reduced the adsorption of P by 25 %. Recovery was close to 100 % for NH4+ and NO3- using KCl solution (1 or 2 M), while high (83 %–93 %) recoveries of Ca, Cu, Fe, K, Mg, Mn and S were found using HCl as an extractant (2–4 M). We found good agreement between the conventional method and the IER method for field conditions. Overall, IER is a powerful tool for the measurement of atmospheric deposition of a broad range of elements as the measurements showed high accuracy. The IER method therefore has the potential to expand current monitoring networks and increase the number of sampling sites.