<i>catena</i>-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ<sup>2</sup> <i>N</i>:<i>S</i> thiocyanato ligands
In the title compound, di-phenyl-tin(IV) diiso-thio-cyanate, [Sn(NCS)<sub>2</sub>(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub>] <sub><i>n</i></sub> or Ph<sub>2</sub>Sn(NCS)<sub>2</sub>, comparatively long tin-nitro-gen and short tin-sulfur bonds prove that the ambidentate iso-thio-cyanate ion acts as a bridge between two neighboring, octa-hedrally coordinated tin atoms. As a result, the mol-ecules lose their individuality in favor of a layered coordination polymer that represents a new type of mol-ecular inter-actions in the structural chemistry of diorganotin(IV) dihalides/pseudohalides. The tin atom is located on a center of inversion.
Authors
- Hans Reuter (ORCID: https://orcid.org/0000-0002-1251-0783)
- Ann-Kathrin Pancratz
- Anne Kamrowski
Institutions
- Osnabrück University (DE)
Publication Details
- Journal
- IUCrData
- Published
- 2024-11-19
- DOI
- https://doi.org/10.1107/s2414314624010939
- Citations
- 1
- Primary Topic
- Organometallic Compounds Synthesis and Characterization
- Type
- article
- Field-Weighted Citation Impact
- 0.25
Funders
- Deutsche Forschungsgemeinschaft