Cu-incorporated NH<sub>2</sub>-MIL-125(Ti): a versatile visible-light-driven platform for enhanced photocatalytic H<sub>2</sub> generation and CO<sub>2</sub> photoconversion
Here, we present for the first time an efficient platform for simultaneous H<sub>2</sub> generation and CO<sub>2</sub> conversion into HCOOH, utilizing a Cu-incorporated NH<sub>2</sub>-MIL-125(Ti) material with triethanolamine as the sacrificial agent. When subjected to light, Cu-NH<sub>2</sub>-MIL-125(Ti) exhibits a remarkable enhancement in H<sub>2</sub> generation, with a 30-fold increase under UV-Vis light and an 8-fold increase under visible irradiation compared to the pristine MOF. The study on the CO<sub>2</sub> photoreduction ability of Cu-NH<sub>2</sub>-MIL-125(Ti) indicated successful conversion into formic acid yielding 62.4 μmol g<sub>cat</sub><sup>-1</sup> under visible irradiation. This notable improvement in photocatalytic activity can be attributed to the heightened light absorption capacity and efficient charge transportation and separation mechanisms inherent in Cu-NH<sub>2</sub>-MIL-125(Ti). Furthermore, the stability of the Cu-NH<sub>2</sub>-MIL-125(Ti) photocatalyst remains steady even after 24 hours of continuous irradiation. The theoretical simulations suggest that Cu introduction effectively reduces the bandgap while leaving the position and composition of the valence band unaffected.
Authors
- Adriana Zaleska‐Medynska (ORCID: https://orcid.org/0000-0003-3817-296X)
- Krzysztof Matus (ORCID: https://orcid.org/0000-0002-4015-5600)
- Alicja Mikołajczyk (ORCID: https://orcid.org/0000-0002-0019-8323)
- Mirosława Pawlyta (ORCID: https://orcid.org/0000-0001-9072-3306)
- Magdalena Miodyńska (ORCID: https://orcid.org/0000-0001-7273-3252)
- Mateusz A. Baluk (ORCID: https://orcid.org/0000-0003-1174-5182)
- Joanna Dołżonek (ORCID: https://orcid.org/0000-0001-5595-7764)
- Aleksandra Pieczyńska (ORCID: https://orcid.org/0000-0003-0920-8118)
- M. Krawczyk (ORCID: https://orcid.org/0000-0001-5241-9610)
- Tomasz Klimczuk (ORCID: https://orcid.org/0000-0002-7089-4631)
- Anna Pancielejko (ORCID: https://orcid.org/0000-0002-2184-1912)
- Anna Gołąbiewska (ORCID: https://orcid.org/0000-0002-1787-9934)
- Henry P. Pinto (ORCID: https://orcid.org/0000-0001-8438-888X)
- Hanna Głowienke
Institutions
- Silesian University of Technology (PL)
- Gdańsk University of Technology (PL)
- Universidad Yachay Tech (EC)
- University of Gdańsk (PL)
- Institute of Physical Chemistry (PL)
- Polish Academy of Sciences (PL)
Publication Details
- Journal
- Materials Horizons
- Published
- 2024-11-15
- DOI
- https://doi.org/10.1039/d4mh01116c
- Citations
- 8
- Primary Topic
- Advanced Photocatalysis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.82
Funders
- Narodowe Centrum Badań i Rozwoju
- Norway Grants
- EEA Grants