Mn-doped WSe <sub>2</sub> as an efficient electrocatalyst for hydrogen production and as anode material for lithium-ion batteries
The ongoing energy crisis has made it imperative to develop low-cost, easily fabricated, yet efficient materials. It is highly desirable for these nanomaterials to function effectively in multiple applications. Among transition metal dichalcogenides, tungsten diselenide (WSe<sub>2</sub>) shows great promise but remains understudied. In this work, we doped WSe<sub>2</sub> with Mn using a simple hydrothermal method. The resulting material exhibited excellent electrocatalytic activity for the hydrogen evolution reaction, achieving a low overpotential of -0.28 V <i>vs.</i> RHE at -10 mA cm<sup>-2</sup>, enhanced conductivity, and high stability and durability. Moreover, as an anode material in lithium-ion batteries, the Mn-doped WSe<sub>2</sub> outperformed pristine WSe<sub>2</sub>, reaching initial discharge capacities of 1223 and 922 mA h g<sup>-1</sup>, respectively. Additionally, the Mn-doped material maintained a significantly higher discharge capacity of 201 mA h g<sup>-1</sup> compared to intact WSe<sub>2</sub>, which had 68 mA h g<sup>-1</sup> after 150 cycles. This work offers novel insights into designing efficient bifunctional nanomaterials using transition metal dichalcogenides.
Authors
- Eva Olsson (ORCID: https://orcid.org/0000-0002-3791-9569)
- Antonia Kagkoura (ORCID: https://orcid.org/0000-0002-6294-7887)
- Shuangying Wei (ORCID: https://orcid.org/0000-0003-2698-4661)
- Zdeněk Sofer (ORCID: https://orcid.org/0000-0002-1391-4448)
- Jan Luxa (ORCID: https://orcid.org/0000-0001-9076-5389)
- Filipa M. Oliveira (ORCID: https://orcid.org/0000-0001-7268-3144)
- Lunjie J. Zeng (ORCID: https://orcid.org/0000-0002-4564-7217)
Institutions
- Chalmers University of Technology (SE)
- University of Chemistry and Technology, Prague (CZ)
Publication Details
- Journal
- Nanoscale
- Published
- 2024-11-15
- DOI
- https://doi.org/10.1039/d4nr04348k
- Citations
- 9
- Primary Topic
- Electrocatalysts for Energy Conversion
- Type
- article
- Field-Weighted Citation Impact
- 0.92
Funders
- Stiftelsen för Strategisk Forskning
- Ministerstvo Školství, Mládeže a Tělovýchovy
- Vetenskapsrådet