Mn-doped WSe <sub>2</sub> as an efficient electrocatalyst for hydrogen production and as anode material for lithium-ion batteries

The ongoing energy crisis has made it imperative to develop low-cost, easily fabricated, yet efficient materials. It is highly desirable for these nanomaterials to function effectively in multiple applications. Among transition metal dichalcogenides, tungsten diselenide (WSe<sub>2</sub>) shows great promise but remains understudied. In this work, we doped WSe<sub>2</sub> with Mn using a simple hydrothermal method. The resulting material exhibited excellent electrocatalytic activity for the hydrogen evolution reaction, achieving a low overpotential of -0.28 V <i>vs.</i> RHE at -10 mA cm<sup>-2</sup>, enhanced conductivity, and high stability and durability. Moreover, as an anode material in lithium-ion batteries, the Mn-doped WSe<sub>2</sub> outperformed pristine WSe<sub>2</sub>, reaching initial discharge capacities of 1223 and 922 mA h g<sup>-1</sup>, respectively. Additionally, the Mn-doped material maintained a significantly higher discharge capacity of 201 mA h g<sup>-1</sup> compared to intact WSe<sub>2</sub>, which had 68 mA h g<sup>-1</sup> after 150 cycles. This work offers novel insights into designing efficient bifunctional nanomaterials using transition metal dichalcogenides.

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Publication Details

Journal
Nanoscale
Published
2024-11-15
DOI
https://doi.org/10.1039/d4nr04348k
Citations
9
Primary Topic
Electrocatalysts for Energy Conversion
Type
article
Field-Weighted Citation Impact
0.92

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article

Mn-doped WSe 2 as an efficient electrocatalyst for hydrogen production and as anode material for lithium-ion batteries

Eva Olsson, Antonia Kagkoura, Shuangying Wei, Zdeněk Sofer et al.
9 citations
Nanoscale
Electrocatalysts for Energy Conversion
0.92
article

Mn-doped WSe 2 as an efficient electrocatalyst for hydrogen production and as anode material for lithium-ion batteries

Eva Olsson, Antonia Kagkoura, Shuangying Wei, Zdeněk Sofer, Jan Luxa, Filipa M. Oliveira, Lunjie J. Zeng
article en
9 citations

Abstract

The ongoing energy crisis has made it imperative to develop low-cost, easily fabricated, yet efficient materials. It is highly desirable for these nanomaterials to function effectively in multiple applications. Among transition metal dichalcogenides, tungsten diselenide (WSe<sub>2</sub>) shows great promise but remains understudied. In this work, we doped WSe<sub>2</sub> with Mn using a simple hydrothermal method. The resulting material exhibited excellent electrocatalytic activity for the hydrogen evolution reaction, achieving a low overpotential of -0.28 V <i>vs.</i> RHE at -10 mA cm<sup>-2</sup>, enhanced conductivity, and high stability and durability. Moreover, as an anode material in lithium-ion batteries, the Mn-doped WSe<sub>2</sub> outperformed pristine WSe<sub>2</sub>, reaching initial discharge capacities of 1223 and 922 mA h g<sup>-1</sup>, respectively. Additionally, the Mn-doped material maintained a significantly higher discharge capacity of 201 mA h g<sup>-1</sup> compared to intact WSe<sub>2</sub>, which had 68 mA h g<sup>-1</sup> after 150 cycles. This work offers novel insights into designing efficient bifunctional nanomaterials using transition metal dichalcogenides.

NanoscaleVol. 17(2)
Chalmers University of Technology (SE), University of Chemistry and Technology, Prague (CZ)
Stiftelsen för Strategisk Forskning, Ministerstvo Školství, Mládeže a Tělovýchovy, Vetenskapsrådet
Affordable and clean energy
Openalex Percentile: Top 29%
Electrocatalysts for Energy Conversion
0.92
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