2,4-Dichloro-6-{<i>N</i>-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol

The title compound, C<sub>14</sub>H<sub>8</sub>Cl<sub>2</sub>F<sub>3</sub>NO, was synthesized by the condensation between tri-fluoro-methyl-aniline and di-chloro-salicyl-aldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an ortho-rhom-bic <i>Pbca</i> (<i>Z</i> = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the mol-ecules pack together to form a zigzag pattern along the <i>c</i> axis.

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IUCrData
Published
2024-11-06
DOI
https://doi.org/10.1107/s2414314624010745
Primary Topic
Fluorine in Organic Chemistry
Type
article
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0.00

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article

2,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol

Koop Lammertsma, Alfred Muller, Zizipho Xantini
IUCrData
Fluorine in Organic Chemistry
article

2,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol

Koop Lammertsma, Alfred Muller, Zizipho Xantini
article en

Abstract

The title compound, C<sub>14</sub>H<sub>8</sub>Cl<sub>2</sub>F<sub>3</sub>NO, was synthesized by the condensation between tri-fluoro-methyl-aniline and di-chloro-salicyl-aldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an ortho-rhom-bic <i>Pbca</i> (<i>Z</i> = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the mol-ecules pack together to form a zigzag pattern along the <i>c</i> axis.

IUCrDataVol. 9(11)
University of Johannesburg (ZA)
National Research Foundation, University of Johannesburg
Clean water and sanitation
Openalex Percentile: Top 84%
Fluorine in Organic Chemistry
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