Chiral Cp<sup><i>x</i></sup>Rh<sup>III</sup>-catalyzed enantioselective C–H annulation to access fused tricyclic sulfur-stereogenic and medium-sized aza-heterocycles
Chiral Cp x Rh-catalyzed enantioselective sp 2 C–H bond activation/annulation reactions give S-stereogenic poly-heterocyclic sulfoximines in up to 99% ee. The tricyclic products can be converted into 10-membered S-stereogenic products upon oxidation.
Authors
- Muhammad Suleman (ORCID: https://orcid.org/0000-0003-3286-2329)
- Yuping Xiong
- Shujuan Xu
- Zhiyuan Chen (ORCID: https://orcid.org/0000-0002-5159-7287)
Institutions
- Hangzhou City University
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-11-15
- DOI
- https://doi.org/10.1039/d4qo01749h
- Citations
- 9
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 2.25
Funders
- National Natural Science Foundation of China