Isoreticular Contraction in Dicopper Paddle‐Wheel‐Based Metal‐Organic Frameworks to Enhance C₂H₂/CO₂ Separation

Achieving a balance between high selectivity and uptake is a formidable challenge for the purification of acetylene from mixtures with carbon dioxide, particularly when seeking to maximize both C₂H₂ adsorption capacity and C₂H₂/CO₂ separation selectivity in crystalline porous materials. In this study, leveraging the principles of reticular chemistry, we selected two tetracarboxylate-based linkers and combined them with Cu²⁺ ions to synthesize two isoreticular dicopper paddle-wheel-based metal-organic frameworks (MOFs): Cu-TPTC (terphenyl-3,3',5,5'-tetracarboxylic acid, H₄TPTC) and Cu-ABTC (3,3,5,5-azobenzenetetracarboxylic acid, H₄ABTC). The structural and sorption analyses revealed that Cu-ABTC, despite having slightly smaller pores due to the strategic replacement of a phenyl ring with an azo group between two tetratopic ligands, maintains high porosity compared to Cu-TPTC. Furthermore, Cu-ABTC outperforms Cu-TPTC in terms of C₂H₂ adsorption capacity (196 cm³ g^-1 at 298 K and 1 bar) and C₂H₂/CO₂ separation selectivity (16.5~5.6). These findings were corroborated by dynamic breakthrough experiments and computational modeling. This research highlights the potential of the isoreticular contraction strategy in enhancing MOFs for sophisticated gas adsorption and separation processes.