1,1,3,3-Tetraphenyl-1,3-bis(<i>N</i>-methylacetamidomethyl)1,3-disiloxane

1,1,3,3-Tetraphenyl-1,3-bis(N-methylacetamidomethyl)-1,3-disiloxane is formed as a result of mild hydrolysis N-[chloro(diphenyl)silyl]methyl-N-methylacetamide. Its structure was studied by NMR spectroscopy and X-ray diffraction analysis. This is the first example of a neutral (O–Si) chelate siloxane with the coordination unit C=O→SiС3OSi.

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Publication Details

Journal
Журнал Общей Химии
Published
2024-10-14
DOI
https://doi.org/10.31857/s0044460x24050071
Primary Topic
Crystal structures of chemical compounds
Type
article
Field-Weighted Citation Impact
0.00
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article

1,1,3,3-Tetraphenyl-1,3-bis(N-methylacetamidomethyl)1,3-disiloxane

N. F. Lazareva, I. М. Lazarev, Irina V. Sterkhova
Журнал Общей Химии
Crystal structures of chemical compounds
article

1,1,3,3-Tetraphenyl-1,3-bis(N-methylacetamidomethyl)1,3-disiloxane

N. F. Lazareva, I. М. Lazarev, Irina V. Sterkhova
article en

Abstract

1,1,3,3-Tetraphenyl-1,3-bis(N-methylacetamidomethyl)-1,3-disiloxane is formed as a result of mild hydrolysis N-[chloro(diphenyl)silyl]methyl-N-methylacetamide. Its structure was studied by NMR spectroscopy and X-ray diffraction analysis. This is the first example of a neutral (O–Si) chelate siloxane with the coordination unit C=O→SiС3OSi.

Журнал Общей ХимииVol. 94(5)
A.E. Favorsky Irkutsk Institute of Chemistry (RU)
Clean water and sanitation
Openalex Percentile: Top 84%
Crystal structures of chemical compounds
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