Redispersible Acrylic Ester Polymers: Effect of Polymer Property Changes Due to Polymerization Method Modification and Functional Additives on the Performance of Polymer Cement Mortar

This paper presents an experimental study aimed at improving the performance of polymer cement mortar by evaluating the properties of acrylic ester redispersible polymers, synthesized using a change in polymerization method from emulsion monomer to monomer dropwise addition methods, along with the use of a functional additive in the form of a foaming agent. To achieve the research objectives, a polymer with a glass transition temperature of -11 °C was synthesized by fixing the monomer ratio, particle-size distribution, and glass transition temperature, and the physical properties of the polymer cement mortar were assessed. The results showed that polymers synthesized using the modified polymerization method increased elongation at break and possessed a 35% smaller average particle size. The use of the foaming agent also resulted in enhanced tensile strength. The polymer cement mortars made with these respective polymers demonstrated improvements in compressive strength 11~25%, flexural strength 53~77%, bond strength 78~113%, volumetric changes 65~88%, and water absorption 30~70%. These findings suggest that changes in the polymerization method and the incorporation of functional additives influence the average particle size and air entrainment control properties of the polymers, thereby positively impacting the performance of the cement hydrates.