Influence of the Structure of Carbamoylmethylphosphine Oxides on the Extraction of Lanthanides(III) from Nitric Acid Solutions in the Presence of Dinonylnaphtalenesulfonic Acid

It was found that the extraction of lanthanides(III) from nitric acid solutions with solutions of carbamoylmethylphosphine oxides increases significantly in the presence of dinonylnaphthalene sulfonic acid. The stoichiometry of the extracted complexes was determined, and the influence of the composition of the aqueous phase, the nature of the organic solvent, and the structure of carbamoylmethylphosphine oxides on the efficiency of extraction of metal ions into the organic phase was considered.

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Journal
Журнал Общей Химии
Published
2024-11-13
DOI
https://doi.org/10.31857/s0044460x24060106
Primary Topic
Radioactive element chemistry and processing
Type
article
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article

Influence of the Structure of Carbamoylmethylphosphine Oxides on the Extraction of Lanthanides(III) from Nitric Acid Solutions in the Presence of Dinonylnaphtalenesulfonic Acid

В. К. Карандашев, Elena V. Sharova, Alexander N. Turanov, Оleg I. Аrtyushin
Журнал Общей Химии
Radioactive element chemistry and processing
article

Influence of the Structure of Carbamoylmethylphosphine Oxides on the Extraction of Lanthanides(III) from Nitric Acid Solutions in the Presence of Dinonylnaphtalenesulfonic Acid

В. К. Карандашев, Elena V. Sharova, Alexander N. Turanov, Оleg I. Аrtyushin
article en

Abstract

It was found that the extraction of lanthanides(III) from nitric acid solutions with solutions of carbamoylmethylphosphine oxides increases significantly in the presence of dinonylnaphthalene sulfonic acid. The stoichiometry of the extracted complexes was determined, and the influence of the composition of the aqueous phase, the nature of the organic solvent, and the structure of carbamoylmethylphosphine oxides on the efficiency of extraction of metal ions into the organic phase was considered.

Журнал Общей ХимииVol. 94(6)
A. N. Nesmeyanov Institute of Organoelement Compounds (RU), Osipyan Institute of Solid State Physics RAS (RU), Institute of Microelectronics Technology and High Purity Materials (RU)
Clean water and sanitation
Openalex Percentile: Top 84%
Radioactive element chemistry and processing
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