Thermal and Luminescent Properties of Multi-Ligand Complexes of Europium(III) with Pyrazine-2-carboxylic Acid

Eu(III) compounds with pyrazine-2-carboxylic acid and nitrogen- and phosphorus-containing neutral ligands were synthesized. Using the methods of chemical elemental and thermal analysis and IR spectroscopy, the composition of the complexes and the method of coordination of carboxylate ions were established. The most thermally stable compounds have been identified. The luminescent characteristics of complex compounds have been studied. It was found that the maximum luminescence intensity is characteristic of europium(III) pyrazinate with triphenylphosphine oxide. The morphological structure and dispersion of the complexes were determined.

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Journal
Журнал Общей Химии
Published
2024-11-13
DOI
https://doi.org/10.31857/s0044460x24060116
Primary Topic
Lanthanide and Transition Metal Complexes
Type
article
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article

Thermal and Luminescent Properties of Multi-Ligand Complexes of Europium(III) with Pyrazine-2-carboxylic Acid

V. G. Kuryavy, Л. Д. Попов, I. V. Kalinovskaya, A. N. Zadorozhnaya
Журнал Общей Химии
Lanthanide and Transition Metal Complexes
article

Thermal and Luminescent Properties of Multi-Ligand Complexes of Europium(III) with Pyrazine-2-carboxylic Acid

V. G. Kuryavy, Л. Д. Попов, I. V. Kalinovskaya, A. N. Zadorozhnaya
article en

Abstract

Eu(III) compounds with pyrazine-2-carboxylic acid and nitrogen- and phosphorus-containing neutral ligands were synthesized. Using the methods of chemical elemental and thermal analysis and IR spectroscopy, the composition of the complexes and the method of coordination of carboxylate ions were established. The most thermally stable compounds have been identified. The luminescent characteristics of complex compounds have been studied. It was found that the maximum luminescence intensity is characteristic of europium(III) pyrazinate with triphenylphosphine oxide. The morphological structure and dispersion of the complexes were determined.

Журнал Общей ХимииVol. 94(6)
Southern Federal University (RU), Vladivostok State Medical University (RU), Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences (RU), Ministry of Health of the Russian Federation (RU)
Clean water and sanitation
Openalex Percentile: Top 87%
Lanthanide and Transition Metal Complexes
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