DIPEA-induced Si–H activation of siloxane for hydrosilylation polymerization <i>via</i> metal-free photocatalysis
A visible light-driven metal-free hydrosilylation reaction catalyzed by the photooxidation catalyst 3DPAFIPN and the base DIPEA was reported. Mechanistic studies revealed that the reaction is a free radical reaction and thermodynamically feasible.
Authors
- Hangcen Xie
- Pingping Lou
- Hua‐Feng Fei (ORCID: https://orcid.org/0000-0002-9983-2725)
- Zhijie Zhang (ORCID: https://orcid.org/0000-0002-0139-3892)
- Bin Huang (ORCID: https://orcid.org/0000-0002-5407-6209)
- Rui Xu
Institutions
- Chinese Academy of Sciences (CN)
- Institute of Chemistry (CN)
- University of Chinese Academy of Sciences (CN)
Publication Details
- Journal
- Green Chemistry
- Published
- 2024-11-13
- DOI
- https://doi.org/10.1039/d4gc04501g
- Citations
- 4
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 1.00