Spatiotemporal Evolution Mine Groundwater’s Hydrogeochemical Characteristics Under Influence of Mining and Grouting in Gubei Coal Mine, China

Geological conditions or human activities will affect the hydrochemical characteristics and formation mechanism of mine groundwater to varying degrees. The northern part of the Beiyi mining area of Gubei Coal Mine is taken as the research area in this study. Based on the data of 52 groups of limestone water (Taihui water) samples in the primary environment, in the mining stage and after grouting, the spatial and temporal variation trend of the chemical characteristics of Taihui water was studied by means of constant index mathematical statistics, a Piper diagram, total ionic salinity, correlation analysis, the ion ratio method and the saturation index. The purpose of this study is to analyze the influence of special geological structures, mining activities and grouting treatment on the formation process of the chemical characteristics of Taihui water, and to provide a basis for the identification of water inrush sources and the resource utilization of deep mine water in this area. The results show that in the three stages, the order of cation concentration is Na+ + K+ > Ca2+ > Mg2+, and the order of anion concentration is changed from Cl− > SO42− > HCO3− to Cl− > HCO3− > SO42−. The hydrochemical type is the most abundant in the mining stage, and tends to be unified after grouting. The dissolution of carbonate minerals, gypsum, rock salt and silicate minerals; cation exchange; pyrite oxidation; and the mixing of grouting precipitation liquid mainly occur in the limestone water. These effects are enhanced or weakened due to the influence of pumping and drainage and grouting precipitation liquid. The results of this study may be beneficial to the sustainable utilization of deep groundwater resources in other similar mines, and promote the establishment of data management and identification mechanisms of water inrush sources in deep coal seams.