Possibilities For Using Ionic Liquids In The Polymerization Process

Abstract The paper investigates the polymerization of various methacrylate esters in different ionic liquids (ILs) and compares the results with those obtained in traditional organic solvents, particularly benzene. The study highlights the influence of ILs on the polymerization process, focusing on factors such as polymer yield, average molecular weight, and thermal stability. The results indicate a relatively higher degree of polymerization in ILs compared to benzene under identical conditions. Additionally, polymers synthesized in ILs exhibit higher average molecular weights and thermal stability. The observed differences are attributed to the unique properties of ILs, such as low chain transfer rate constants and the ability to stabilize active radicals during polymerization. The findings underscore the potential of ILs as promising reaction media for polymer synthesis, offering improved efficiency and polymer properties compared to conventional organic solvents.