Hydrogeochemical Characteristics and Formation Mechanisms of High-Arsenic Groundwater in the North China Plain: Insights from Hydrogeochemical Analysis and Unsupervised Machine Learning

Hydrochemical data were utilized in this study to elucidate the hydrogeochemical characteristics and genesis of high-arsenic groundwater in the North China Plain, employing both traditional hydrogeochemical analysis and unsupervised machine learning techniques. The findings indicate that the predominant hydrochemical types of groundwater in the study area are HCO3-Ca·Na and SO4·Cl-Na·Ca. The primary mechanism influencing groundwater chemistry has been identified as rock weathering. The unsupervised machine learning framework incorporates various methods, such as principal component analysis (PCA), non-negative matrix factorization (NMF), machine learning models (gradient boosting trees and random forests), and cluster analysis to explore the characteristics and genesis of groundwater hydrochemical types within the study area. This study demonstrated that the formation mechanism of high-arsenic groundwater results from multiple interacting factors.