Copper‐Catalyzed Ring‐Opening Hydrosilylation and Hydroboration of Arylidenecyclopropanes
Comprehensive Summary Arylidenecyclopropanes (ACPs) are highly strained substrates that can be readily utilized for diverse transformations. This study showcases the outcomes of copper‐catalyzed ring‐opening hydrosilylation and hydroboration reactions of ACPs, showcasing precise cleavage of C—C bonds. The reaction presents an effective and convenient method for producing homoallylic silanes and boronates.
Authors
- Yun‐He Xu (ORCID: https://orcid.org/0000-0001-8817-0626)
- Zhenyu Xiao (ORCID: https://orcid.org/0000-0002-9439-8958)
- Zi‐Lu Wang (ORCID: https://orcid.org/0000-0002-1187-7508)
Institutions
- University of Science and Technology of China (CN)
Publication Details
- Journal
- Chinese Journal of Chemistry
- Published
- 2024-11-11
- DOI
- https://doi.org/10.1002/cjoc.202400811
- Citations
- 4
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 1.00
Funders
- National Natural Science Foundation of China
- Chinese Academy of Sciences
- Nankai University
- Hangzhou Normal University