Provenance and Paleo-Environment of the Late Carboniferous Bauxite Formations in Southern Shanxi

The Carboniferous Benxi Formation in southern Shanxi of North China has significant bauxite resource potential; however, the source of its metallogenic material and its sedimentary environment remain unclear. The microscopy, X-ray diffraction, X-ray fluorescence spectroscopy, and inductively coupled plasma mass spectrometry methods were applied in this study to examine the mineralogical, petrographic, and geochemical characteristics. Geochemical proxies of La/Y, Sr/Ba, Al2O3/TiO2, Zr/Sc, Th/Sc, La/Sc, and Th/Co were analyzed to investigate the paleo-depositional environment and provenance of the aluminum-bearing strata. The findings indicate that diaspores are the primary ore minerals in bauxite, while kaolinite and rutile are the predominant gangue minerals. Both the bauxite and claystone/aluminous rocks exhibit high enrichment in Li, Bi, and U, with relative enrichment in In, Sb, Th, Nb, and Ta. Li is notably concentrated in the claystone/aluminous rocks, reaching up to 1994.00 μg/g, primarily occurring in cookeite and boehmite, while U is highly concentrated in the bauxite. The aluminum-bearing strata were primarily formed under alkaline-reducing conditions, with changes in acidity and alkalinity of the environment during the sedimentary diagenetic process. Marine transgressions significantly impacted the sedimentary environment of the aluminum-bearing strata, and the paleoclimate was characterized as hot and humid. The principal factors contributing to enrichment of aluminum in the sedimentary basin were the in situ weathering of aluminum-rich source rocks and the transport of clastic materials from high-aluminum source rocks. The source rocks were closely associated with intermediate-acidic magmatic rocks and potentially related to the weathering of Ordovician carbonates.