Design of Silicon-Based Anode Materials for High Energy Density Li-Ion Batteries

Compared to other types of batteries, lithium batteries have an extremely high energy density, which means they can store more energy while maintaining a smaller size and weight. The ideal electrode material must have a high lithium ion capacity to store many lithium ions. In addition, the electrode material must have good electronic conductivity to promote lithium ions' rapid entry and exit. However, traditional carbon materials have limited theoretical specific capacity, and the transmission of lithium-ion batteries in traditional materials is limited, resulting in a significant decrease in capacity. Silicon has a theoretical capacity of up to 4200mAh/g, more than ten times the capacity of commercial graphite negative electrodes. In addition, silicon and lithium can undergo alloying reactions to form Li Si alloys, which helps improve the material's specific capacity. This article first summarizes the advantages of electric vehicles and lithium-ion batteries. Then, the benefits and challenges of using silicon-based materials as negative electrodes for lithium-ion batteries were elaborated in detail, and finally, the prospects of silicon-based materials in lithium-ion battery applications were summarized. This article has reference significance in improving the energy density of lithium-ion batteries.

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Publication Details

Journal
Highlights in Science Engineering and Technology
Published
2024-11-07
DOI
https://doi.org/10.54097/yr3my387
Primary Topic
Advancements in Battery Materials
Type
article
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article

Design of Silicon-Based Anode Materials for High Energy Density Li-Ion Batteries

Haonan Cui
Highlights in Science Engineering and Technology
Advancements in Battery Materials
article

Design of Silicon-Based Anode Materials for High Energy Density Li-Ion Batteries

Haonan Cui
article en

Abstract

Compared to other types of batteries, lithium batteries have an extremely high energy density, which means they can store more energy while maintaining a smaller size and weight. The ideal electrode material must have a high lithium ion capacity to store many lithium ions. In addition, the electrode material must have good electronic conductivity to promote lithium ions' rapid entry and exit. However, traditional carbon materials have limited theoretical specific capacity, and the transmission of lithium-ion batteries in traditional materials is limited, resulting in a significant decrease in capacity. Silicon has a theoretical capacity of up to 4200mAh/g, more than ten times the capacity of commercial graphite negative electrodes. In addition, silicon and lithium can undergo alloying reactions to form Li Si alloys, which helps improve the material's specific capacity. This article first summarizes the advantages of electric vehicles and lithium-ion batteries. Then, the benefits and challenges of using silicon-based materials as negative electrodes for lithium-ion batteries were elaborated in detail, and finally, the prospects of silicon-based materials in lithium-ion battery applications were summarized. This article has reference significance in improving the energy density of lithium-ion batteries.

Highlights in Science Engineering and TechnologyVol. 116
Affordable and clean energy
Openalex Percentile: Top 82%
Advancements in Battery Materials
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