Porous activated carbon electrodes derived from Eleusine coracana biowaste in electric double layer capacitors: Nanoarchitectonics and performance

The development of high-performance supercapacitors from biowaste is crucial for advancing sustainable and renewable energy storage technologies. In this study, we report the fabrication of electrodes for high-performance supercapacitors using porous carbon derived from red millet ( Eleusine coracana ) straw. Porous carbon was synthesized via a two-step chemical activation process using KOH, resulting in a hierarchical pore structure comprising macro-, meso-, and micropores. The red millet-based porous carbon electrodes, assembled in a two-electrode symmetrical supercapacitor, exhibited a specific capacitance of 68 Fg⁻ 1 at a current density of 0.5 Ag⁻ 1 in a 1 M Na₂SO₄ aqueous electrolyte. At a mass loading of 5 mg per electrode, the system demonstrated a specific capacitance of 300 Fg⁻ 1 at 1 Ag⁻ 1 , with an energy density of 9.1 Whkg⁻ 1 and a power density of 1.86 kWkg⁻ 1 , as determined from galvanostatic charge-discharge measurements. Additionally, the supercapacitor showed excellent cyclic stability, retaining 98.78% of its initial capacitance after 5000 cycles at 10 Ag⁻ 1 . These findings highlight the potential of porous carbon derived from agricultural biowaste for scalable applications in electric double-layer capacitors. • The study focuses on developing high-performance supercapacitors using porous carbon derived from red millet straw, an agricultural biowaste. • Through a two-step KOH activation, a hierarchical pore structure was achieved, enhancing energy storage capabilities. • The porous carbon electrodes exhibited 300 Fg⁻ 1 at 1 Ag⁻ 1 , with an energy density of 9.1 Whkg⁻ 1 and a power density of 1.86 kWkg⁻ 1 . • The system demonstrated a specific capacitance of 68 Fg⁻ 1 at 0.5 Ag⁻ 1 , and 98.78 % cyclic stability after 5000 cycles, showcasing its potential for scalable supercapacitor applications.