Electrochemical Synthesis of Alkenylsulfonates from Alkynes, <scp>NaHSO<sub>3</sub></scp> and Alcohols
Comprehensive Summary Alkenylsulfonates are commonly encountered in medicinal chemistry, polymer chemistry, and organic synthesis. In this research, an electrochemical reaction involving alkynes, NaHSO 3 , and alcohols has been developed. This method yields functionalized alkenylsulfonates in good yields with broad functional group tolerance. Mechanism studies indicate that anodic oxidation of inorganic sulfite, radical insertion process, and HAT process are involved in this transformation.
Authors
- Jie Wu (ORCID: https://orcid.org/0000-0002-9865-180X)
- Yi Hu (ORCID: https://orcid.org/0000-0001-9319-5692)
- Qianqian Chen (ORCID: https://orcid.org/0000-0002-4520-7799)
- Jinhang Zhou
- S. Ye (ORCID: https://orcid.org/0000-0003-3229-0746)
- Xiaoman Wang (ORCID: https://orcid.org/0009-0004-4929-1184)
Institutions
- Nanjing Tech University (CN)
- Chinese Academy of Sciences (CN)
- Shanghai Institute of Organic Chemistry (CN)
- Henan Normal University (CN)
- Taizhou University (CN)
Publication Details
- Journal
- Chinese Journal of Chemistry
- Published
- 2024-11-07
- DOI
- https://doi.org/10.1002/cjoc.202400962
- Citations
- 9
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 2.25
Funders
- Henan Normal University
- National Natural Science Foundation of China
- Natural Science Foundation of Zhejiang Province