Diastereoselective Anomeric C(sp<sup>3</sup>)−H Cyclization Towards the Design of New Cyclophane‐Braced Glycopeptides
Abstract Here we report a macrocyclization route towards the synthesis of glycophane peptides by a selective C−H arylation of the anomeric bond. This approach demonstrates the power of Pd‐catalysis C−H activation to access unusual cyclic peptides.
Authors
- Sakna Bazzi (ORCID: https://orcid.org/0000-0003-0183-4819)
- Mehdi A. Beniddir (ORCID: https://orcid.org/0000-0003-2153-4290)
- Juba Ghouilem (ORCID: https://orcid.org/0000-0003-4195-580X)
- Vincent Gandon (ORCID: https://orcid.org/0000-0003-1108-9410)
- Dmytro Ryzhakov (ORCID: https://orcid.org/0000-0002-2777-7480)
- Samir Messaoudi (ORCID: https://orcid.org/0000-0002-4994-9001)
- Ameni Hadj Mohamed
Institutions
- Centre National de la Recherche Scientifique (FR)
- École Polytechnique (FR)
- École Nationale Supérieure de Techniques Avancées (FR)
- Université Paris-Saclay (FR)
- Laboratoire de Synthèse Organique (FR)
- Institut de Chimie Moléculaire et des Matériaux d'Orsay (FR)
Publication Details
- Journal
- Angewandte Chemie
- Published
- 2024-11-08
- DOI
- https://doi.org/10.1002/ange.202418057
- Citations
- 1
- Primary Topic
- Carbohydrate Chemistry and Synthesis
- Type
- article
- Field-Weighted Citation Impact
- 0.25