Lewis Acid‐Catalyzed Isomerization of Donor‐Acceptor Cyclobutanes in the Presence of Thiourea: A New Efficient Route to 2‐ Arylallylmalonates
Abstract A straightforward access to various substituted 2‐arylallylmalonates from readily available donor‐Acceptor (D‐A) cyclobutanes catalyzed by Al(OTf) 3 in the presence of thiourea is reported. This is a new and convenient approach for isomerization of donor‐acceptor cyclobutanes into 2‐arylallylmalonates.
Authors
- Zuliang Chen (ORCID: https://orcid.org/0000-0003-1975-4972)
- Yanqing Zhang (ORCID: https://orcid.org/0000-0001-9030-5876)
- Ruixin Zhao (ORCID: https://orcid.org/0000-0003-3207-8438)
- Jintao Zhang (ORCID: https://orcid.org/0000-0002-4582-6266)
Institutions
- Yichun University (CN)
- State Intellectual Property Office (CN)
Publication Details
- Journal
- ChemistrySelect
- Published
- 2024-11-01
- DOI
- https://doi.org/10.1002/slct.202404202
- Citations
- 1
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.25
Funders
- National Natural Science Foundation of China