3a<i>H</i>,4<i>H</i>,5<i>H</i>,8<i>H</i>,9<i>H</i>,9a<i>H</i>-Cycloocta[<i>d</i>][1,3]dioxole-2-thione

The thio-nocarbonate of <i>trans</i>-cyclo-octenediol, C<sub>9</sub>H<sub>12</sub>O<sub>2</sub>S, crystallizes with a 9/1 disorder in the position of the <i>R,R</i> and <i>S,S</i>-enanti-omers. As a result of <i>trans</i>-annulation, both rings adopt a twist conformation.

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Publication Details

Journal
IUCrData
Published
2024-11-08
DOI
https://doi.org/10.1107/s2414314624010198
Primary Topic
Crystal structures of chemical compounds
Type
article
Field-Weighted Citation Impact
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article

3aH,4H,5H,8H,9H,9aH-Cycloocta[d][1,3]dioxole-2-thione

Heiner Detert, Dieter Schollmeyer, Claudia Kammler
IUCrData
Crystal structures of chemical compounds
article

3aH,4H,5H,8H,9H,9aH-Cycloocta[d][1,3]dioxole-2-thione

Heiner Detert, Dieter Schollmeyer, Claudia Kammler
article en

Abstract

The thio-nocarbonate of <i>trans</i>-cyclo-octenediol, C<sub>9</sub>H<sub>12</sub>O<sub>2</sub>S, crystallizes with a 9/1 disorder in the position of the <i>R,R</i> and <i>S,S</i>-enanti-omers. As a result of <i>trans</i>-annulation, both rings adopt a twist conformation.

IUCrDataVol. 9(11)
Johannes Gutenberg University Mainz (DE)
Openalex Percentile: Top 84%
Crystal structures of chemical compounds
DOIOpen Access PDFOpenAlex
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3a<i>H</i>,4<i>H</i>,5<i>H</i>,8<i>H</i>,9<i>H</i>,9a<i>H</i>-Cycloocta[<i>d</i>][1,3]dioxole-2-thione — Heiner Detert, Dieter Schollmeyer, et al. · IUCrData (2024) | TGRS Research Map | TGRS