Silver‐Mediated Allylation of Aryl Alkenes to Synthesize 1,4‐Dienes
An efficient silver-mediated allylation of aryl alkenes is described, which provides a variety of skipped 1,4-dienes. Without the need for other traditional transition metals or gold, this AgOTf-mediated allylation proceeds smoothly with high regio- and stereoselectivity. Mechanistic and computational studies suggest that this silver-mediated allylation takes place via a Friedel-Crafts-type pathway of aryl alkenes to the silver-activated allyl acetates.
Authors
- Dantong Wang (ORCID: https://orcid.org/0000-0003-2379-8222)
- Zhonghua Xia (ORCID: https://orcid.org/0000-0001-5737-831X)
- Fen Zhao
- Wenqian Du
- Jiawen Wu (ORCID: https://orcid.org/0000-0002-3504-5538)
Institutions
- Beijing Institute of Technology (CN)
- Minzu University of China (CN)
- Yunnan University (CN)
Publication Details
- Journal
- Chemistry - An Asian Journal
- Published
- 2024-11-07
- DOI
- https://doi.org/10.1002/asia.202401228
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Yunnan Provincial Science and Technology Department
- Beijing Institute of Technology Research Fund Program for Young Scholars