Suppression of thermal transport in bent boron arsenide nanoribbons

Boron arsenide (BAs) has emerged as a strong contender for next-generation functional materials, boasting desirable attributes such as high thermal conductivity and ambipolar mobility. However, a critical yet underexplored challenge lies in understanding its heat conduction capabilities under inhomogeneous strain, which is pivotal across various functional devices and operational conditions. Here, through modeling thermal transport in bent BAs and $\mathrm{Si}$ nanoribbons, a striking difference is revealed. Namely, the BAs nanoribbons exhibit nearly twice the reduction in thermal conductivity compared with $\mathrm{Si}$ under identical bending conditions. This significant disparity is driven by two key factors: the pronounced effect of phonon-spectra broadening under strain and the inhomogeneous strain-induced narrowing of the acoustic and optical (ao) gap. Together, these factors relax the originally restricted phonon scattering phase space and fundamentally alter phonon scattering dynamics. Our findings not only offer a new perspective on how heat transfer can be dynamically modulated in BAs, but also provide crucial insights into enhancing thermal performance in BAs-based functional devices.

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Publication Details

Journal
Physical Review Applied
Published
2024-11-07
DOI
https://doi.org/10.1103/physrevapplied.22.054019
Citations
6
Primary Topic
Thermal properties of materials
Type
article
Field-Weighted Citation Impact
0.70

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article

Suppression of thermal transport in bent boron arsenide nanoribbons

Lin Yang, Shuo Qiao, Guohui Jiao, Yi Tao et al.
6 citations
Physical Review Applied
Thermal properties of materials
0.70
article

Suppression of thermal transport in bent boron arsenide nanoribbons

Lin Yang, Shuo Qiao, Guohui Jiao, Yi Tao, J Lyu
article en
6 citations

Abstract

Boron arsenide (BAs) has emerged as a strong contender for next-generation functional materials, boasting desirable attributes such as high thermal conductivity and ambipolar mobility. However, a critical yet underexplored challenge lies in understanding its heat conduction capabilities under inhomogeneous strain, which is pivotal across various functional devices and operational conditions. Here, through modeling thermal transport in bent BAs and $\mathrm{Si}$ nanoribbons, a striking difference is revealed. Namely, the BAs nanoribbons exhibit nearly twice the reduction in thermal conductivity compared with $\mathrm{Si}$ under identical bending conditions. This significant disparity is driven by two key factors: the pronounced effect of phonon-spectra broadening under strain and the inhomogeneous strain-induced narrowing of the acoustic and optical (ao) gap. Together, these factors relax the originally restricted phonon scattering phase space and fundamentally alter phonon scattering dynamics. Our findings not only offer a new perspective on how heat transfer can be dynamically modulated in BAs, but also provide crucial insights into enhancing thermal performance in BAs-based functional devices.

Physical Review AppliedVol. 22(5)
Peking University (CN), Southeast University (CN)
National Natural Science Foundation of China
Affordable and clean energy
Openalex Percentile: Top 29%
Thermal properties of materials
0.70
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Suppression of thermal transport in bent boron arsenide nanoribbons — Lin Yang, Shuo Qiao, et al. · Physical Review Applied (2024) | TGRS Research Map | TGRS