Fluorescent Carbon Dots for Improved Visualization of Latent Fingermarks after Cyanoacrylate Fuming

The use of spectroscopic methods to process fingermark evidence is a key procedure in forensic laboratories for identifying the perpetrator of a crime. However, latent fingermarks must first be developed. While metal powders and dyes are commonly used as chemical developers, recent studies have shown that nanomaterials may offer superior development performance and numerous advantages. Herein, we corroborate this viewpoint reporting the successful utilization of carbon quantum dots (C-dots) as a fluorescent developer for latent fingerprint deposited on aluminum substrates and previously treated with cyanoacrylate fuming. These C-dots exhibit strong blue luminescence driven by emission from both core and surface emissive sites. Owing to the hydrogen bonds established between –OH, –COOH, and –NH groups from C-dots and –C≡ N and –COOR in polymerized cyanoacrylate, C-dots adhere strongly to fingermark ridges from various individuals, significantly enhancing contrast and details within pores and ridge morphology. The adsorbed C-dots are stable, and the photoluminescent mark remains visible even after washing the developed fingermarks with water.

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Institutions

Publication Details

Journal
ACS Applied Nano Materials
Published
2024-11-07
DOI
https://doi.org/10.1021/acsanm.4c05048
Citations
12
Primary Topic
Forensic Fingerprint Detection Methods
Type
article
Field-Weighted Citation Impact
6.31

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article

Fluorescent Carbon Dots for Improved Visualization of Latent Fingermarks after Cyanoacrylate Fuming

Guilherme Martins, Emı́lia Sousa, Karina P.M. Frin, Rodrigo Meneses de Barros et al.
12 citations
ACS Applied Nano Materials
Forensic Fingerprint Detection Methods
6.31
article

Fluorescent Carbon Dots for Improved Visualization of Latent Fingermarks after Cyanoacrylate Fuming

Guilherme Martins, Emı́lia Sousa, Karina P.M. Frin, Rodrigo Meneses de Barros, Marco Antônio de Souza, Leonardo G. Paterno
article en
12 citations

Abstract

The use of spectroscopic methods to process fingermark evidence is a key procedure in forensic laboratories for identifying the perpetrator of a crime. However, latent fingermarks must first be developed. While metal powders and dyes are commonly used as chemical developers, recent studies have shown that nanomaterials may offer superior development performance and numerous advantages. Herein, we corroborate this viewpoint reporting the successful utilization of carbon quantum dots (C-dots) as a fluorescent developer for latent fingerprint deposited on aluminum substrates and previously treated with cyanoacrylate fuming. These C-dots exhibit strong blue luminescence driven by emission from both core and surface emissive sites. Owing to the hydrogen bonds established between –OH, –COOH, and –NH groups from C-dots and –C≡ N and –COOR in polymerized cyanoacrylate, C-dots adhere strongly to fingermark ridges from various individuals, significantly enhancing contrast and details within pores and ridge morphology. The adsorbed C-dots are stable, and the photoluminescent mark remains visible even after washing the developed fingermarks with water.

ACS Applied Nano MaterialsVol. 7(22)
Universidade de Brasília (BR), Centro Universitário do Distrito Federal (BR), Universidade Federal do ABC (BR), Federal Police of Brazil (BR)
Fundação de Amparo à Pesquisa do Estado de São Paulo, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior, Conselho Nacional de Desenvolvimento Científico e Tecnológico, Fundação de Apoio à Pesquisa do Distrito Federal
Openalex Percentile: Top 3%
Forensic Fingerprint Detection Methods
6.31
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