Synthesis of oxa-bridged carbocycles <i>via</i> rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles

A method for cooperative rhodium/Lewis acid-catalyzed cycloadditions of carbonyl ylides with donor–acceptor (D–A) strained carbocycles is described. It affords structurally diverse oxa-bridged carbocycles with high efficiency and stereoselectivity.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2024-11-06
DOI
https://doi.org/10.1039/d4qo01831a
Citations
6
Primary Topic
Cyclopropane Reaction Mechanisms
Type
article
Field-Weighted Citation Impact
1.50
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article

Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles

Pei Nian Liu, Lingling Wang, Xingguang Li, Jiale Li
6 citations
Organic Chemistry Frontiers
Cyclopropane Reaction Mechanisms
1.50
article

Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles

Pei Nian Liu, Lingling Wang, Xingguang Li, Jiale Li
article en
6 citations

Abstract

A method for cooperative rhodium/Lewis acid-catalyzed cycloadditions of carbonyl ylides with donor–acceptor (D–A) strained carbocycles is described. It affords structurally diverse oxa-bridged carbocycles with high efficiency and stereoselectivity.

Organic Chemistry FrontiersVol. 12(2)
East China University of Science and Technology (CN), China Pharmaceutical University (CN)
Openalex Percentile: Top 19%
Cyclopropane Reaction Mechanisms
1.50
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