Pore Structure Modulation in Kirigamic Zeolitic Imidazolate Framework
Abstract Paper crafts, such as origami and kirigami, have become an interdisciplinary research theme transportable from art to science, and further to engineering. Kirigami‐inspired architectural design strategies allow the establishment of three‐dimensional (3D) mechanical linkages with unprecedented mechanical properties. Herein, we report a crystalline zeolitic imidazolate framework (ZIF), displaying folding mechanics based on a kirigami tessellation, originated from the double‐corrugation surface (DCS) pattern. Pressure‐ and guest‐induced responses demonstrate the kirigami mechanism of the ZIF, wherein imidazolate linkers act as hinges, controlling pore dimensionality, resembling the check valve‐adapted mechanical manifold. This discovery of the kirigami tessellation inside a flexible ZIF reveals foldable mechanics at the molecular level.
Authors
- Wen‐Long Xue (ORCID: https://orcid.org/0000-0003-0778-2300)
- Hoi Ri Moon (ORCID: https://orcid.org/0000-0002-6967-894X)
- Sebastian Henke (ORCID: https://orcid.org/0000-0003-1502-6038)
- Wonyoung Choe (ORCID: https://orcid.org/0000-0003-0957-1187)
- Andreas Schneemann (ORCID: https://orcid.org/0000-0001-6801-2735)
- Joohan Nam (ORCID: https://orcid.org/0000-0001-5123-418X)
- Eunji Jin (ORCID: https://orcid.org/0000-0002-2103-6526)
- Leila Abylgazina (ORCID: https://orcid.org/0000-0001-8754-4374)
- Hyunchul Oh (ORCID: https://orcid.org/0000-0001-6258-0002)
- Jürgen Getzschmann
- Hong Kyu Lee (ORCID: https://orcid.org/0000-0003-4833-6120)
Institutions
- Ewha Womans University (KR)
- TU Dortmund University (DE)
- Ulsan National Institute of Science and Technology (KR)
- Technische Universität Dresden (DE)
Publication Details
- Journal
- Angewandte Chemie
- Published
- 2024-11-06
- DOI
- https://doi.org/10.1002/ange.202417137
- Primary Topic
- Spectroscopy and Chemometric Analyses
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Ulsan National Institute of Science and Technology
- National Research Foundation of Korea