Solid-State Reversible Phase Transition and Photoluminescence Properties of Organic-Inorganic Hybrid Halide: (BTPA)<sub>2</sub>MnBr<sub>4</sub>
Multifunctional materials have long been a popular research area, with organic-inorganic hybrids frequently utilized due to their diverse properties and versatile assembly techniques. In this context, a novel Mn-based organic-inorganic hybrid compound (BTPA)<sub>2</sub>MnBr<sub>4</sub>(<b>1</b>) was prepared, with strong green photoluminescence, phase transition under thermal stimulation, and two reversible dielectric-state switches. This compound exhibits strong green photoluminescence under ultraviolet excitation, boasting a quantum yield of 44.36%. Furthermore, it demonstrates a reversible ferroelastic phase transition at 358/348 K. The integration of temperature and photosensitivity in compound <b>1</b> opens up new avenues for the development and exploration of a broader spectrum of multifunctional phase transition materials.
Authors
- Xiuzhen Yu (ORCID: https://orcid.org/0000-0003-3136-7289)
- H. T. Tan (ORCID: https://orcid.org/0009-0009-9351-9656)
- Yao Liu (ORCID: https://orcid.org/0000-0001-5334-8287)
- Jinzhen Liu (ORCID: https://orcid.org/0000-0003-0496-2859)
- Zhiguo Chen (ORCID: https://orcid.org/0000-0002-8242-4784)
- Yiyuan Liu (ORCID: https://orcid.org/0000-0002-7022-6422)
- Shengkai Li (ORCID: https://orcid.org/0000-0003-2803-5654)
Institutions
- Jiangxi University of Science and Technology (CN)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2024-11-06
- DOI
- https://doi.org/10.1021/acs.inorgchem.4c02359
- Citations
- 3
- Primary Topic
- Perovskite Materials and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.63
Funders
- Education Department of Jiangxi Province