Rhodium-Catalyzed Trifluoromethoxylation of Allenylic Trichloroacetimidates
The first rhodium-catalyzed trifluoromethoxylation of allenylic trichloroacetimidates has been reported. The products were obtained through a procedure using trifluoromethyl arylsulfonate (TFMS) as the trifluoromethoxy source with a yield up to 76% by identifying the ligand of diene. The reaction proceeds under mild reaction conditions with excellent functional group tolerance and complete regiocontrol.
Authors
- Pingping Tang (ORCID: https://orcid.org/0000-0002-8296-5695)
- Yangdong Hou
- Yicheng Luo
Institutions
- Nankai University (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2024-11-05
- DOI
- https://doi.org/10.1021/acs.orglett.4c03676
- Citations
- 2
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.42
Funders
- National Natural Science Foundation of China
- Nankai University
- Natural Science Foundation of Tianjin City
- National Key Research and Development Program of China
- Fundamental Research Funds for the Central Universities