Synthesis and structure of pentakis(2-aminopyridinium) nonavanado(V)tellurate(VI)
In the title compound, (C<sub>5</sub>H<sub>7</sub>N<sub>2</sub>)<sub>5</sub>[TeV<sub>9</sub>O<sub>28</sub>], the tellurium and vanadium atoms are statistically disordered over two of the ten metal-atom sites in the [TeV<sub>9</sub>O<sub>28</sub>]<sup>5-</sup> heteropolyanion. The anions stack along [100] and are extended into a three-dimensional supra-molecular network through N-H⋯O and weak C-H⋯O hydrogen bonds involving the self-assembled 2-amino-pyridinium penta-mers, which are linked by C-H⋯π and π-π stacking inter-actions. The most important contributions to the Hirshfeld surface arise from O⋯H/H⋯O (54.8%), H⋯H (17.8%) and C⋯H/H⋯C (13.4%) contacts.
Authors
- Ahlem Maalaoui (ORCID: https://orcid.org/0009-0006-5053-8628)
- Samah Akriche (ORCID: https://orcid.org/0000-0002-3401-6399)
- Mohamed Rzaigui
- Houda Mrad
Institutions
- University of Carthage (TN)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2024-11-04
- DOI
- https://doi.org/10.1107/s2056989024010533
- Primary Topic
- Organometallic Compounds Synthesis and Characterization
- Type
- article
- Field-Weighted Citation Impact
- 0.00