Boron/Difluoroamino (B/NF2) Composites Prepared Through an Energetic Fluorinated-Centerd Surface Modification Strategy to Enhance Their Ignition and Combustion Characteristics

To enhance the ignition and combustion characteristics of boron (B), in this study, a suitable, energetic fluorinated group (NF₂) that can improve energy and promote combustion efficiency was utilized and B/NF₂ composites (B/PDB) with three different particle sizes (10-20 μm, <5 μm, and 0.5-2 μm) were prepared through energetic fluorinated surface modifications with a PDB layer, a copolymer of difluoroaminomethyl-3-methylethoxybutane and 3,3'-bis(azidomethyl)oxetane, coated on the surface of B. The morphology and structure of B/PDB were characterized via the FTIR, SEM, TEM, and XPS techniques. The results indicate that all B/PDB particle sizes were successfully coated by NF₂ on the surfaces of B particles through the PDB layer. The TG curves in the thermal analyses were used to determine the amount of the PDB layer of B/PDB with different particle sizes. Based on the DSC curves, NF₂ of composites with better catalysis during ammonium perchlorate (AP) decomposition. Additionally, the effects of NF₂ on both B/PDB and B/PDB with AP were investigated through PY-GC/MS, ignition, and combustion. Compared with pure B, NF₂ significantly improved the thermal conductivity, thereby decreasing the ignition delay of B/PDB, and the ignition delay of B/PDB with AP. The combustion of B/PDB and AP was more intense, extending the combustion duration, forming volatile fluorine compounds, and increasing combustion reaction efficiency. In general, this energetic fluorinated-centred surface modification has potential applications to enhance the ignition and combustion characteristics in B.