Dynamic Magnetic Susceptibility Method in Studies of Coordination Compounds

The measurement of the dynamic magnetic susceptibility is a universal method, which is used for the evaluation of magnetic properties of single molecule magnets by scientists all over the world. An information in the Russian scientific literature that can be useful for practical mastering of this method is presently insufficient. To fill this gap, in this work we present a detailed procedure of a magnetochemical experiment for observing slow magnetic relaxation in coordination compounds of 3d- and 4f-element ions and the complete characterization of the dynamics of the magnetic behavior. Special attention is given to usually omitted but important details related to all stages of studying the magnetic relaxation dynamics. The main variants of sample preparation are described, the logics of the construction of a measuring sequence and the procedure of experimental data processing are discussed, and advantages and drawbacks of some programs of the calculation of magnetic relaxation dynamics data are considered. The main concepts and equations used in experimental data analysis are presented, and the primary conclusions that can be made from the obtained results are proposed.

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Publication Details

Journal
Координационная химия
Published
2024-11-05
DOI
https://doi.org/10.31857/s0132344x24070011
Primary Topic
Magnetism in coordination complexes
Type
article
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article

Dynamic Magnetic Susceptibility Method in Studies of Coordination Compounds

А. В. Ротов, Konstantin A. Babeshkin, Nikolay N. Efimov
Координационная химия
Magnetism in coordination complexes
article

Dynamic Magnetic Susceptibility Method in Studies of Coordination Compounds

А. В. Ротов, Konstantin A. Babeshkin, Nikolay N. Efimov
article en

Abstract

The measurement of the dynamic magnetic susceptibility is a universal method, which is used for the evaluation of magnetic properties of single molecule magnets by scientists all over the world. An information in the Russian scientific literature that can be useful for practical mastering of this method is presently insufficient. To fill this gap, in this work we present a detailed procedure of a magnetochemical experiment for observing slow magnetic relaxation in coordination compounds of 3d- and 4f-element ions and the complete characterization of the dynamics of the magnetic behavior. Special attention is given to usually omitted but important details related to all stages of studying the magnetic relaxation dynamics. The main variants of sample preparation are described, the logics of the construction of a measuring sequence and the procedure of experimental data processing are discussed, and advantages and drawbacks of some programs of the calculation of magnetic relaxation dynamics data are considered. The main concepts and equations used in experimental data analysis are presented, and the primary conclusions that can be made from the obtained results are proposed.

Координационная химияVol. 50(7)
Russian Academy of Sciences (RU), Institute of General and Inorganic Chemistry (BG)
Openalex Percentile: Top 89%
Magnetism in coordination complexes
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Dynamic Magnetic Susceptibility Method in Studies of Coordination Compounds — А. В. Ротов, Konstantin A. Babeshkin, et al. · Координационная химия (2024) | TGRS Research Map | TGRS