Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones
An efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.
Authors
- Xiaobo He (ORCID: https://orcid.org/0000-0001-7072-1768)
- Jiang Long (ORCID: https://orcid.org/0000-0003-0010-5067)
- Liqin Qiu (ORCID: https://orcid.org/0000-0003-1703-3530)
- Bendu Pan (ORCID: https://orcid.org/0000-0001-5400-6721)
- Yaqi Zhang (ORCID: https://orcid.org/0000-0002-5158-2683)
- Yunru Wu
Institutions
- Sun Yat-sen University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-11-05
- DOI
- https://doi.org/10.1039/d4qo01771d
- Citations
- 6
- Primary Topic
- Asymmetric Hydrogenation and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.95