<scp>GGR</scp> Handbook of Rock and Mineral Analysis Chapter 13 Laser‐Induced Breakdown Spectroscopy (<scp>LIBS</scp>)

This chapter (Laser‐Induced Breakdown Spectroscopy (LIBS)) is a contribution to the Geostandards and Geoanalytical Research Handbook of Rock and Mineral Analysis – an online textbook that is a fully revised and updated edition of A Handbook of Silicate Rock Analysis (P. J. Potts, 1987, Blackie, Glasgow). Chapter 13 (from Section 3 of the handbook dealing with microbeam techniques) provides first a history of the development of laser‐induced breakdown spectroscopy, and of the LIBS process, followed by an examination of the fundamental principles of LIBS and its instrumentation. Discussion is then provided on the preparation of sample material, LIBS matrix effects and signal processing. Different modes of compositional analysis that can be tackled by LIBS are described, including quantitative measurement (covering isotope measurements), compositional mapping, depth profiling and the determination of physical properties of geological materials. The recent tandem coupling of LIBS with laser ablation ICP‐MS instrumentation is explored. Finally, a suite of examples of LIBS analyses of silicate rocks and minerals is provided, demonstrating the utility of this measurement principle in rapid compositional assessment, detailed petrological studies and microgeochemical mapping.