MnO<sub>2</sub> Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials

MnO<sub>2</sub> nanowires coated with conjugated microporous polymers (CMP) are applied as triboelectric energy harvesting materials. The tribopositive performance of the CMP shells is enhanced with the assistance of MnO<sub>2</sub> nanowires (MnO<sub>2</sub> NW), likely due to cationic charge transfer from the tribopositive CMP layers to the surface Mn<sup>2+</sup> and Mn<sup>3+</sup> species of MnO<sub>2</sub> NW. This is supported by model studies. The MnO<sub>2</sub>@CMP-2 with sub-10 nm thick CMP layers shows promising triboelectric output voltages up to 576 V and a maximum power density of 1.31 mW cm<sup>-2</sup>. Spring-assisted triboelectric nanogenerators fabricated with MnO<sub>2</sub>@CMP-2/PVP-3 films are used as power supplies to operate electronic devices.

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Publication Details

Journal
Advanced Science
Published
2024-11-03
DOI
https://doi.org/10.1002/advs.202409917
Citations
3
Primary Topic
Advanced Sensor and Energy Harvesting Materials
Type
article
Field-Weighted Citation Impact
0.55

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article

MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials

Hyunjin Jung, Seung Uk Son, Dong‐Min Lee, Sang‐Woo Kim et al.
3 citations
Advanced Science
Advanced Sensor and Energy Harvesting Materials
0.55
article

MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials

Hyunjin Jung, Seung Uk Son, Dong‐Min Lee, Sang‐Woo Kim, Tae‐Ho Kim, Jina Park
article en
3 citations

Abstract

MnO<sub>2</sub> nanowires coated with conjugated microporous polymers (CMP) are applied as triboelectric energy harvesting materials. The tribopositive performance of the CMP shells is enhanced with the assistance of MnO<sub>2</sub> nanowires (MnO<sub>2</sub> NW), likely due to cationic charge transfer from the tribopositive CMP layers to the surface Mn<sup>2+</sup> and Mn<sup>3+</sup> species of MnO<sub>2</sub> NW. This is supported by model studies. The MnO<sub>2</sub>@CMP-2 with sub-10 nm thick CMP layers shows promising triboelectric output voltages up to 576 V and a maximum power density of 1.31 mW cm<sup>-2</sup>. Spring-assisted triboelectric nanogenerators fabricated with MnO<sub>2</sub>@CMP-2/PVP-3 films are used as power supplies to operate electronic devices.

Advanced ScienceVol. 11(48)
Yonsei University (KR), Sungkyunkwan University (KR)
National Research Foundation of Korea
Affordable and clean energy
Openalex Percentile: Top 36%
Advanced Sensor and Energy Harvesting Materials
0.55
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