New Method for the Synthesis of 1,3-Diallyl-1,1,3,3-tetramethyldisiloxane
A new method for the synthesis of 1,3-diallyl-1,1,3,3-tetramethyldisiloxane is proposed that includes several steps: the synthesis of dicellosolvoxy(dimethyl)silane by the transesterification reaction followed by obtaining allyl(cellosolvoxy)dimethylsilane from it under the action of the Grignard reagent and its condensation. The resulting product was characterized by 1H, 13C, and 29Si NMR spectroscopy as well as gas-liquid chromatography. The yield of the product was more than 90%, its purity was 99%.
Authors
- Aziz M. Muzafarov (ORCID: https://orcid.org/0000-0002-3050-3253)
- Kseniya A. Bezlepkina (ORCID: https://orcid.org/0000-0001-9141-3289)
- Sergey A. Milenin (ORCID: https://orcid.org/0000-0001-6887-3711)
- Sofia N. Ardabevskaia (ORCID: https://orcid.org/0000-0002-2767-1125)
- F. D. Krylov
Publication Details
- Journal
- INEOS OPEN
- Published
- 2024-11-04
- DOI
- https://doi.org/10.32931/io2415a
- Primary Topic
- Electron Spin Resonance Studies
- Type
- article
- Field-Weighted Citation Impact
- 0.00