Ru(II)‐catalyzed ortho C−H Arylation of Heterocyclic Biaryls
Abstract Ru(II)‐Pheox complexes are known catalysts for carbene insertion reactions. Herein we teach them a new trick: how to perform ortho C−H arylation processes! Our operationally simple protocol tolerates structurally diverse directing groups and both aryl iodides and diaryliodonium salts as transfer groups.
Authors
- Erick M.C. Pinheiro
- Denison de Oliveira Couto
- Caio C. Oliveira (ORCID: https://orcid.org/0000-0002-2277-8003)
Institutions
- Universidade Estadual de Campinas (UNICAMP) (BR)
Publication Details
- Journal
- Asian Journal of Organic Chemistry
- Published
- 2024-11-04
- DOI
- https://doi.org/10.1002/ajoc.202400463
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Fundação de Amparo à Pesquisa do Estado de São Paulo