In-Cylinder Sampling Analysis of Soot Precursors during Bio-Derived Lactone Combustion in a Single-Cylinder Diesel Engine

<div class="section abstract"><div class="htmlview paragraph">The development of new fuels for internal combustion engines (ICE) requires further technical support by understanding the pollutant formation mechanism in various phases of combustion so that emissions can be minimised. This research will therefore utilize a bespoke in-cylinder sampling system to analyse the precursors of Polycyclic Aromatic Hydrocarbons (PAHs) and Particulate Matter (PM) during bio-derived lactone combustion in a single-cylinder diesel engine. The sampling system was composed of a poppet-type in-cylinder sampling valve that displaced one of the engine’s intake valves and protruded into the combustion chamber beyond the flame quenching layer, and a Gas Chromatography Flame Ionization Detector (GC-FID) that analysed the samples. The sampling valve was electromagnetically actuated, and its operation was referenced to the engine crank shaft encoder allowing the valve to open at any crank angle degree (CAD) within a timing resolution of 0.2 CAD. Lactones are oxygenated carbon ring molecules that can be generated from a diverse range of feedstocks. Initial experiments found that some lactones exhibited similar ignition and combustion characteristics compared to fossil diesel, suggesting that these fuels could displace a proportion of fossil fuel usage. During the lactone combustion, the sampling valve was first opened at <i>Top Dead Center (TDC)</i> to investigate intermediate species arising from lactone decomposition during ignition delay and the start of combustion, while the subsequent samples were taken at 20 CAD and 40 CAD after TDC. Intermediate species including C1-C6 molecules such as ethylene, acetylene, acetaldehyde, ethanol, 1,3 butadiene, and benzene were observed in high levels in the samples. The chemical types and the relative abundance of them during the progress of combustion provided insights into the lactone decomposition pathway and the PAH formation mechanism in diesel engine combustion.</div></div>