Enhanced Degradation of Norfloxacin Under Visible Light by S-Scheme Fe2O3/g–C3N4 Heterojunctions

S-scheme Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions were successfully fabricated by the ultrasonic assistance method to remove norfloxacin (NOR) under visible light irradiation. The synthesized catalysts were well studied through various techniques. The obtained Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions exhibited an optimal photocatalytic degradation of 94.7% for NOR, which was 1.67 and 1.28 times higher than using Fe<sub>2</sub>O<sub>3</sub> and g-C<sub>3</sub>N<sub>4</sub> alone, respectively. In addition, the kinetic constant of NOR removal with Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composites was about 0.6631 h<sup>-1</sup>, and NOR photo-deegradation was still 86.7% after four cycles. The enhanced photocatalytic activity may be mainly attributed to the formation of S-scheme Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions with built-in electric fields, which were beneficial to the separation and transfer of photostimulated charge carriers. Furthermore, a possible photo-degradation mechanism of NOR for S-scheme Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions is described.

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Publication Details

Journal
Molecules
Published
2024-11-04
DOI
https://doi.org/10.3390/molecules29215212
Citations
10
Primary Topic
Advanced Photocatalysis Techniques
Type
article
Field-Weighted Citation Impact
1.02

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article

Enhanced Degradation of Norfloxacin Under Visible Light by S-Scheme Fe2O3/g–C3N4 Heterojunctions

Guang Lü, Jiling Liang, Guizhou Gu, Zhen Chen et al.
10 citations
Molecules
Advanced Photocatalysis Techniques
1.02
article

Enhanced Degradation of Norfloxacin Under Visible Light by S-Scheme Fe2O3/g–C3N4 Heterojunctions

Guang Lü, Jiling Liang, Guizhou Gu, Zhen Chen, Wei Li, Zheng Li, Qiuju Han
article en
10 citations

Abstract

S-scheme Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions were successfully fabricated by the ultrasonic assistance method to remove norfloxacin (NOR) under visible light irradiation. The synthesized catalysts were well studied through various techniques. The obtained Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions exhibited an optimal photocatalytic degradation of 94.7% for NOR, which was 1.67 and 1.28 times higher than using Fe<sub>2</sub>O<sub>3</sub> and g-C<sub>3</sub>N<sub>4</sub> alone, respectively. In addition, the kinetic constant of NOR removal with Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composites was about 0.6631 h<sup>-1</sup>, and NOR photo-deegradation was still 86.7% after four cycles. The enhanced photocatalytic activity may be mainly attributed to the formation of S-scheme Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions with built-in electric fields, which were beneficial to the separation and transfer of photostimulated charge carriers. Furthermore, a possible photo-degradation mechanism of NOR for S-scheme Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions is described.

MoleculesVol. 29(21)
Shenyang Ligong University (CN), Liaoning Shihua University (CN)
National Science Foundation, Strong, National Natural Science Foundation of China, Natural Science Foundation of Liaoning Province
Clean water and sanitation
Openalex Percentile: Top 27%
Advanced Photocatalysis Techniques
1.02
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Enhanced Degradation of Norfloxacin Under Visible Light by S-Scheme Fe2O3/g–C3N4 Heterojunctions — Guang Lü, Jiling Liang, et al. · Molecules (2024) | TGRS Research Map | TGRS