Enhanced Degradation of Norfloxacin Under Visible Light by S-Scheme Fe2O3/g–C3N4 Heterojunctions
S-scheme Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions were successfully fabricated by the ultrasonic assistance method to remove norfloxacin (NOR) under visible light irradiation. The synthesized catalysts were well studied through various techniques. The obtained Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions exhibited an optimal photocatalytic degradation of 94.7% for NOR, which was 1.67 and 1.28 times higher than using Fe<sub>2</sub>O<sub>3</sub> and g-C<sub>3</sub>N<sub>4</sub> alone, respectively. In addition, the kinetic constant of NOR removal with Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composites was about 0.6631 h<sup>-1</sup>, and NOR photo-deegradation was still 86.7% after four cycles. The enhanced photocatalytic activity may be mainly attributed to the formation of S-scheme Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions with built-in electric fields, which were beneficial to the separation and transfer of photostimulated charge carriers. Furthermore, a possible photo-degradation mechanism of NOR for S-scheme Fe<sub>2</sub>O<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunctions is described.
Authors
- Guang Lü (ORCID: https://orcid.org/0000-0001-8392-2980)
- Jiling Liang (ORCID: https://orcid.org/0000-0002-2051-8515)
- Guizhou Gu
- Zhen Chen (ORCID: https://orcid.org/0000-0002-1854-1476)
- Wei Li (ORCID: https://orcid.org/0000-0002-5796-4930)
- Zheng Li (ORCID: https://orcid.org/0000-0003-0412-293X)
- Qiuju Han (ORCID: https://orcid.org/0000-0001-5584-6781)
Institutions
- Shenyang Ligong University (CN)
- Liaoning Shihua University (CN)
Publication Details
- Journal
- Molecules
- Published
- 2024-11-04
- DOI
- https://doi.org/10.3390/molecules29215212
- Citations
- 10
- Primary Topic
- Advanced Photocatalysis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 1.02
Funders
- National Science Foundation
- Strong
- National Natural Science Foundation of China
- Natural Science Foundation of Liaoning Province