A Constrained Geometry Fluorenyl Amido Magnesium Catalyst for Amine‐Borane Dehydrocoupling

Abstract A fluorenyl amido constrained geometry magnesium complex is described, which was obtained by deprotonation of the corresponding neutral ligand system with dibutyl magnesium. Its structure was determined by SC‐XRD and it was shown to be a potent catalyst for amine‐borane dehydrogenation/dehydrocoupling.

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Publication Details

Journal
Zeitschrift für anorganische und allgemeine Chemie
Published
2024-11-03
DOI
https://doi.org/10.1002/zaac.202400136
Primary Topic
Hydrogen Storage and Materials
Type
article
Field-Weighted Citation Impact
0.00

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article

A Constrained Geometry Fluorenyl Amido Magnesium Catalyst for Amine‐Borane Dehydrocoupling

André Schäfer, Bernd Morgenstern, Jessica Lambert
Zeitschrift für anorganische und allgemeine Chemie
Hydrogen Storage and Materials
article

A Constrained Geometry Fluorenyl Amido Magnesium Catalyst for Amine‐Borane Dehydrocoupling

André Schäfer, Bernd Morgenstern, Jessica Lambert
article en

Abstract

Abstract A fluorenyl amido constrained geometry magnesium complex is described, which was obtained by deprotonation of the corresponding neutral ligand system with dibutyl magnesium. Its structure was determined by SC‐XRD and it was shown to be a potent catalyst for amine‐borane dehydrogenation/dehydrocoupling.

Zeitschrift für anorganische und allgemeine ChemieVol. 650(23)
Saarland University (DE)
Deutsche Forschungsgemeinschaft, Universität des Saarlandes
Clean water and sanitation
Openalex Percentile: Top 88%
Hydrogen Storage and Materials
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