Linker Group Fluorination Boosts Photovoltaic Performance of Branch‐Connected Dimerized Acceptors

Branch-connected dimerized acceptors can take full advantages of four end units in enhancing molecular packing comparing to that of terminal-connected ones, thus potentially reaching the best balance between stability and power conversion efficiency (PCE) of organic solar cells (OSCs). Herein, two branch-connected dimerized acceptors, namely D1 and D2, are developed by employing bithiophene and difluorinated bithiophene as linker groups, respectively. Induced by the fluorine atoms on linker group, D2 affords a larger molar extinction coefficient, more importantly, the optimized nanoscale film morphology and superior charge transport behavior comparing to D1. Consequently, D2-based binary OSCs render a good PCE of 16.66%, outperforming that of 15.08% for D1-based ones. This work highlights the great significance of linker group screening in designing high-performance branch-connected dimerized acceptors.