Paired electrocatalysis enabled oxidative coupling of styrenes with alkyl radicals
A paired electrocatalysis strategy for intermolecular oxidative cross-dehydrocoupling between styrenes and ethers or <i>p</i>-methylphenol derivatives using ketone as a mild oxidant is described. This approach enables the generation of Csp<sup>3</sup> carbon-centered radicals through anodic oxidation, followed by reductive coupling of ketones at the cathode, ultimately yielding valuable oxidative alkylation products.
Authors
- Dan Li (ORCID: https://orcid.org/0000-0003-3461-5751)
- Tao Shen (ORCID: https://orcid.org/0000-0002-2028-152X)
- Dong Li (ORCID: https://orcid.org/0000-0002-8633-9958)
- Ling Zhang (ORCID: https://orcid.org/0000-0002-4991-1134)
- Yu Peng (ORCID: https://orcid.org/0000-0002-3862-632X)
Institutions
- Fujian Medical University (CN)
- Shanghai Jiao Tong University (CN)
- Zhongshan Hospital of Xiamen University (CN)
- Eastern Institute of Technology, Ningbo
Publication Details
- Journal
- Organic & Biomolecular Chemistry
- Published
- 2024-10-31
- DOI
- https://doi.org/10.1039/d4ob01605j
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Science Foundation
- Natural Science Foundation of Fujian Province
- Shanghai Jiao Tong University
- Fundamental Research Funds for the Central Universities