β-to-β Singly Linked Subphthalocyanine Dimers with Effective π-Conjugation
In this work, a series of π-conjugated Subphthalocyanine dimers assembled by simple π-bridges were efficiently synthesized through metal-catalyzed reactions. Despite being singly linked, these readily accessible arrays exhibit excellent π-electron communication, significantly perturbing the orbital distribution of conventional SubPcs and inducing notable alterations in their optical properties. The findings presented here demonstrate the potential of SubPcs for constructing curved porphyrin arrays with well-conjugated skeletons and intriguing functionalities.
Authors
- Tomás Torres⊗ (ORCID: https://orcid.org/0000-0001-9335-6935)
- Marta Gómez‐Gómez (ORCID: https://orcid.org/0009-0008-6058-2985)
- Jorge Labella (ORCID: https://orcid.org/0000-0001-5665-2778)
- Daniel Holgado
Institutions
- Madrid Institute for Advanced Studies (ES)
- Universidad Autónoma de Madrid (ES)
Publication Details
- Journal
- Organic Letters
- Published
- 2024-10-31
- DOI
- https://doi.org/10.1021/acs.orglett.4c03407
- Citations
- 3
- Primary Topic
- Porphyrin and Phthalocyanine Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.35
Funders
- Alexander von Humboldt-Stiftung
- Comunidad de Madrid
- Ministerio de Ciencia, Innovación y Universidades
- Ministerio de Educación, Cultura y Deporte
- Ministerio de Economía y Competitividad