Cover Picture: Photocatalyst‐Free Wavelength‐Dependant Sequential Ring Transformations of Pyrazolo[1,2‐<i>a</i>]pyrazolones (Adv. Synth. Catal. 21/2024)

The inside cover picture illustrates novel wavelength-dependent transformations of pyrazolo[1,2-a]pyrazolones into 3D-rich heterocyclic systems. The robot with flashlights represents how two distinct products can be easily obtained by simply adjusting the irradiation wavelength, leading to either 1,2-diazepines through ring expansion or tricyclic product via consecutive 4π-electrocyclization. These transformations are highly stereoselective, do not require photocatalysts or additives, and can be easily scaled up. For more details, see the Research Article by I. Kulašić, B. Štefane and co-workers (I. Kulašić, N. Petek, H. Brodnik, U. Grošelj, J. Svete, B. Štefane, Adv. Synth. Catal. 2024, 366, XXXX–XXXX; DOI: 10.1002/adsc.202400684)

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Publication Details

Journal
Advanced Synthesis & Catalysis
Published
2024-10-31
DOI
https://doi.org/10.1002/adsc.202401227
Primary Topic
Synthesis and Reactions of Organic Compounds
Type
article
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article

Cover Picture: Photocatalyst‐Free Wavelength‐Dependant Sequential Ring Transformations of Pyrazolo[1,2‐a]pyrazolones (Adv. Synth. Catal. 21/2024)

Uroš Grošelj, Bogdan Štefane, Helena Brodnik, Nejc Petek et al.
Advanced Synthesis & Catalysis
Synthesis and Reactions of Organic Compounds
article

Cover Picture: Photocatalyst‐Free Wavelength‐Dependant Sequential Ring Transformations of Pyrazolo[1,2‐a]pyrazolones (Adv. Synth. Catal. 21/2024)

Uroš Grošelj, Bogdan Štefane, Helena Brodnik, Nejc Petek, Jurij Svete, Ines Kulašić
article en

Abstract

The inside cover picture illustrates novel wavelength-dependent transformations of pyrazolo[1,2-a]pyrazolones into 3D-rich heterocyclic systems. The robot with flashlights represents how two distinct products can be easily obtained by simply adjusting the irradiation wavelength, leading to either 1,2-diazepines through ring expansion or tricyclic product via consecutive 4π-electrocyclization. These transformations are highly stereoselective, do not require photocatalysts or additives, and can be easily scaled up. For more details, see the Research Article by I. Kulašić, B. Štefane and co-workers (I. Kulašić, N. Petek, H. Brodnik, U. Grošelj, J. Svete, B. Štefane, Adv. Synth. Catal. 2024, 366, XXXX–XXXX; DOI: 10.1002/adsc.202400684)

Advanced Synthesis & CatalysisVol. 366(21)
University of Ljubljana (SI)
Openalex Percentile: Top 86%
Synthesis and Reactions of Organic Compounds
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