Synthesis and crystal structure of 1,3,5-tris[(1<i>H</i>-benzotriazol-1-yl)methyl]-2,4,6-triethylbenzene

In the crystal structure of the title compound, C<sub>33</sub>H<sub>33</sub>N<sub>9</sub>, the tripodal mol-ecule exists in a conformation in which the substituents attached to the central arene ring are arranged in an alternating order above and below the ring plane. The three benzotriazolyl moieties are inclined at angles of 88.3 (1), 85.7 (1) and 82.1 (1)° with respect to the mean plane of the benzene ring. In the crystal, only weak mol-ecular cross-linking involving C-H⋯N hydrogen bonds is observed.

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Publication Details

Journal
Acta Crystallographica Section E Crystallographic Communications
Published
2024-10-31
DOI
https://doi.org/10.1107/s2056989024009988
Primary Topic
Crystal structures of chemical compounds
Type
article
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article

Synthesis and crystal structure of 1,3,5-tris[(1H-benzotriazol-1-yl)methyl]-2,4,6-triethylbenzene

Monika Mazik, Niklas Koch, Sebastian Förster
Acta Crystallographica Section E Crystallographic Communications
Crystal structures of chemical compounds
article

Synthesis and crystal structure of 1,3,5-tris[(1H-benzotriazol-1-yl)methyl]-2,4,6-triethylbenzene

Monika Mazik, Niklas Koch, Sebastian Förster
article en

Abstract

In the crystal structure of the title compound, C<sub>33</sub>H<sub>33</sub>N<sub>9</sub>, the tripodal mol-ecule exists in a conformation in which the substituents attached to the central arene ring are arranged in an alternating order above and below the ring plane. The three benzotriazolyl moieties are inclined at angles of 88.3 (1), 85.7 (1) and 82.1 (1)° with respect to the mean plane of the benzene ring. In the crystal, only weak mol-ecular cross-linking involving C-H⋯N hydrogen bonds is observed.

Acta Crystallographica Section E Crystallographic CommunicationsVol. 80(11)
TU Bergakademie Freiberg (DE)
Clean water and sanitation
Openalex Percentile: Top 85%
Crystal structures of chemical compounds
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