Iminoacylation Reaction of Iodoaniline with [2-B10H9NCCH3]– Anion as a Route to the Preparation of New Boron-Containing Synthons

The reaction of nucleophilic addition of isomers of iodaniline to the nitrile derivative of the closo-decaborate anion has been studied. The structures of the products have been determined using multinuclear NMR and IR spectroscopy, as well as ESI mass spectrometry. The structure of compound (NBu4)[2-B10H9NHC(CH3)HN(2-C6H4I)] was determined by single-crystal X-ray diffraction.

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Publication Details

Journal
Russian Journal of Inorganic Chemistry
Published
2024-10-01
DOI
https://doi.org/10.1134/s0036023624601934
Primary Topic
Boron Compounds in Chemistry
Type
article
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article

Iminoacylation Reaction of Iodoaniline with [2-B10H9NCCH3]– Anion as a Route to the Preparation of New Boron-Containing Synthons

К. Yu. Zhizhin, А. V. Nelyubin, Andrey P. Zhdanov, Н. А. Селиванов et al.
Russian Journal of Inorganic Chemistry
Boron Compounds in Chemistry
article

Iminoacylation Reaction of Iodoaniline with [2-B10H9NCCH3]– Anion as a Route to the Preparation of New Boron-Containing Synthons

К. Yu. Zhizhin, А. V. Nelyubin, Andrey P. Zhdanov, Н. А. Селиванов, A. Yu. Bykov, I. N. Klyukin, Alexey S. Kubasov, Nikolay T. Kuznetsov
article en

Abstract

The reaction of nucleophilic addition of isomers of iodaniline to the nitrile derivative of the closo-decaborate anion has been studied. The structures of the products have been determined using multinuclear NMR and IR spectroscopy, as well as ESI mass spectrometry. The structure of compound (NBu4)[2-B10H9NHC(CH3)HN(2-C6H4I)] was determined by single-crystal X-ray diffraction.

Russian Journal of Inorganic ChemistryVol. 69(10)
NS Kurnakova Institute of General and Inorganic Chemistry (RU)
Openalex Percentile: Top 68%
Boron Compounds in Chemistry
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